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4,9 In humans, nutritional immunity, where host mechanisms have evolved to limit bacterial pathogen access to nutrient metals, alongside host-mediated metal intoxication, are central aspects of the tug-of-war between host and pathogen in infectious disease

An important target of Cu I toxicity is the FeS cluster biogenesis machinery, 165167 as well as FeS clusters of mature enzymes, including dehydratases, where Cu I displaces one or more Fe atoms on what are essentially solvent exposed clusters, 168 potentiating oxidative stress through Fenton chemistry

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